- PII
- S3034630425110078-1
- DOI
- 10.7868/S3034630425110078
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 61 / Issue number 11
- Pages
- 1585-1592
- Abstract
- A new catalyst for Meinwald rearrangement and synthesis of 1,3-dioxolan is proposed for reactions of terminal epoxides as an example. A highly efficient and selective rearrangement in the presence of catalytic quantities of tetraethylammonium iodide was shown. Excellent yields of acetyl derivatives were obtained at this rearrangement. An anomalous condensation of 4-(3,6-dichloro-9-carbazol-9-yl)-3-hydroxybutanenitrile with aldehydes and ketones was discovered. This condensation is accompanied by the elimination of water in an alkaline solution and only derivatives of -butadienes are formed.
- Keywords
- оксираны перегруппировка Мейнвальда 1,3-диоксоланы тетраэтиламмоний иодид
- Date of publication
- 27.03.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 37
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