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RAS Chemistry & Material ScienceЖурнал органической химии Russian Journal of Organic Chemistry

  • ISSN (Print) 0514-7492
  • ISSN (Online) 3034-6304

Reactivity features of -Carboranillithium towards 3,6-Diaryl-1,2,4,5-Tetrazines

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PII
S3034630425070059-1
DOI
10.7868/S3034630425070059
Publication type
Article
Status
Published
Authors
T. D. Moseev
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
D. S. Kopchuk
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
L. A. Smyshliaeva
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
A. N. Tsmokaluk
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
P. A. Slepukhin
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
A. V. Rybakova
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
G. V. Zyryanov
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
M. V. Varaksin
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
V. N. Charushin
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
O. N. Chupakhin
  • Affiliation:
    Institute of Chemical Engineering, Ural Federal University
    I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
    South Ural State University
Volume/ Edition
Volume 61 / Issue number 7
Pages
839-847
Abstract
The reaction of -carboranillithium with 3,6-di(2-pyridyl)-1,2,4,5-tetrazine, considered as an example of the “from challenging to simple” strategy in the chemistry of carbonanes, leads to the previously unknown 3--carboranyl-[1,2,3]triazolo[1,5-]pyridine as a result of cleavage of the tetrazine cycle and subsequent formation of the triazole cycle with nitrogen elimination. The structure of the obtained compound was confirmed by the spectroscopic and X-ray diffraction studies. The reaction mechanism, which was additionally confirmed by quantum-chemical calculations of electron densities and the Fukui function, was proposed.
Keywords
карборан тетразин DFT-расчеты перегруппировка
Date of publication
01.07.2025
Year of publication
2025
Number of purchasers
0
Views
21

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