RAS Chemistry & Material ScienceЖурнал органической химии Russian Journal of Organic Chemistry

  • ISSN (Print) 0514-7492
  • ISSN (Online) 3034-6304

Cyclization of Ethyl [Cyano(4,6-dimethylpyrimidin-2-yl)amino]-acetate

PII
S30346304S0514749225030136-1
DOI
10.7868/S3034630425030136
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 61 / Issue number 3
Pages
322-328
Abstract
Imidazolin-4-one derivatives have been prepared by a reaction of ethyl [cyano(4,6-dimethylpyrimidin-2-yl)amino]acetate (2) with morpholine, piperidine and hydrazides. In the presence of sulfuric acid, cyanoester 2 gives 2-iminooxazolin-5-one which is acylated on the nitrogen atom of imino group and is rearranged to imidzolidin-2,4-dione in the presence of KCNO.
Keywords
пиримидин имидазол оксазол этилхлорацетат цианамид циклизация
Date of publication
25.12.2024
Year of publication
2024
Number of purchasers
0
Views
18

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