- PII
- S30346304S0514749225040073-1
- DOI
- 10.7868/S3034630425040073
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 61 / Issue number 4
- Pages
- 422-435
- Abstract
- Based on the reactions of diastereoselective allylation of (R)-2,3-O-cyclohexylideneelyceraldehyde with methyl 3-(bromomethyl)but-3-enoate and its allylstannyl derivative, unsaturated lactones (6R)- and (6S)-6-[(2R)-1,4-dioxaspiro[4.5]dec-2-yl]-4-methyl-5,6-dihydro-2H-pyran-2-ones were synthesized. After highly diastereoselective reduction, these lactones found application in the implementation of a new retrosynthetic scheme for the preparation of C–C, C–C and C–C building blocks of amphidinolides of the G and H families.
- Keywords
- диастереоселективное аллилирование биомиметика амфидинолиды семейств G и H 2-замещенные аллилбромиды лактоны циклопропанолы
- Date of publication
- 15.12.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 27
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