Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems

Micellar effects in perhydrolysis and base catalyzed hydrolysis of 4-nitrophenyl esters of phosphoric, phosphonic and toluolsulphonic acids in organized microheterogeneous systems based on dicationic (Gemini surfactant, GS – AlkIm–(CH)-ImAlk-2Br, Alk = CH or CH) and monocationic (AlkImCH Br, Alk = CH or CH) surfactants have been analyzed. The effect of concentration of reagents is the main factor responsible for micellar catalysis. Hydroperoxide α-effect described as second order rate constants ratio for perhydrolysis and base catalyzed hydrolysis remains in organized media, and, depending on surfactant/substrate nature, may amount to ~100.

Keywords

экотоксиканты димерные катионные ПАВ пероксигидролиз эффект концентрирования α-эффект

Date of publication

15.12.2025

Year of publication

2025

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References

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GOST	Belousova I., Gaidash T., Kotenko A., Mikhailov V., Prokop'eva T., Razumova N., Turovskaya M. Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems // Russian Journal of Organic Chemistry. – 2025. – V. 61. – Issue number 4 C. 466-474 . URL: https://orgchemras.ru/s30346304s0514749225040135-1/?version_id=119426. DOI: 10.7868/S3034630425040135
MLA	Belousova, I.A, Gaidash, T.S, Kotenko, A.A, Mikhailov, V. A, Prokop'eva, T.M, Razumova, N.G, Turovskaya, M.K "Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems." Russian Journal of Organic Chemistry. 61.4 (2025).:466-474. DOI: 10.7868/S3034630425040135
APA	Belousova I., Gaidash T., Kotenko A., Mikhailov V., Prokop'eva T., Razumova N., Turovskaya M. (2025). Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems. Russian Journal of Organic Chemistry. vol. 61, no. 4, pp.466-474 DOI: 10.7868/S3034630425040135

RAS Chemistry & Material ScienceЖурнал органической химии Russian Journal of Organic Chemistry

Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems

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RAS Chemistry & Material ScienceЖурнал органической химии Russian Journal of Organic Chemistry

Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media. IV. Peroxyhydrolysis of Acylcontaining Compounds in Organized Microheterogenic Systems

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