- PII
- S3034630425070236-1
- DOI
- 10.7868/S3034630425070236
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 61 / Issue number 7
- Pages
- 1029-1032
- Abstract
- Based on the chalcogenfunctionalization reactions of allylicatic acid with tellurium, selenium, and sulfur halides, methods for the synthesis of new bifunctional chalcogenorganic compounds with yields of 86–99 % have been developed. The reactions of sulfur and selenium dihalides yield chalcogenides containing two butyrolactone rings in 97–99 % yields. Reactions with TeCl and TeBr yield trihalogenetellanes with a methylbutyrolactone group. The interaction of TeBr with allylicatic acid in methanol proceeds as methoxytellurination and is accompanied by the transformation of the carboxyl group into a methoxycarbonyl group. Reduction of the trihalogenetellanes with high yields yielded the corresponding ditellurides.
- Keywords
- аллилуксусная кислота дибромид селена дихлорид серы халькогенорганические соединения тетрахлорид теллура тетрабромид теллура циклофункционализация производные бутиролактона
- Date of publication
- 01.07.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 23
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